Let's assume the businessman's original amount of money is $1.
Step 1: Donation to Charity X
2% of $1 is \frac{2}{100} \times 1 = 0.02
After donating to Charity X, the businessman has $1 - 0.02 = 0.98 remaining.
Step 2: Donation to Charity Y
4% of $0.98 is \frac{4}{100} \times 0.98 = 0.0392
After donating to Charity Y, the businessman has $0.98 - 0.0392 = 0.9408 remaining.
Step 3: Donation to Charity Z
6% of $0.9408 is \frac{6}{100} \times 0.9408 = 0.056448
Therefore, the businessman donated 0.056448 out of his original amount of $1 to Charity Z.
Answer: The percentage of his original amount of money donated to Charity Z is 5.645%.