To find the new volume of the gas when the pressure is doubled, we can use Boyle's Law: 
Boyle's Law states: P_1V_1 = P_2V_2 where P_1 and V_1 are the initial pressure and volume, and P_2 and V_2 are the final pressure and volume. Since the temperature is constant, we can use Boyle's Law. 
Given:
 P_1 = 2 atm 
 V_1 = 1 L
 P_2 = 2 \times P_1 = 2 \times 2 = 4 atm
Let's substitute the values into Boyle's Law formula:
 P_1V_1 = P_2V_2 
 2 \times 1 = 4 \times V_2 
 2 = 4V_2 
Solving for V_2 :
 V_2 = \frac{2}{4} 
 V_2 = \frac{1}{2} 
 V_2 = 0.5 L
Therefore, the volume of the gas when the pressure is doubled is \boxed{0.5} L.